Minggu, 03 November 2013

Oxidation Reaction of Cyclohexanol and Cannizzaro Reaction of Benzaldehyde

OXIDATION REACTION OF CYCLOHEXANOL AND CANNIZZARO REACTION OF BENZALDEHYDE

By
Ni Luh Gede Enik Karnila Yanti
Chemistry Education Department, Faculty of Mathematics and Natural Sciences, Ganesha University of Education
email: enikkarnilayanti@yahoo.co.id

Abstract

The aims of the experiment was to (1) undertand the oxidation-reduction reaction of organic compound (2) identify product of the reaction. The compound used are cyclohexanol and benzaldehyde were prepared by the laboratory assistant as the subjects of this experiment. The mechanism and the product of the redox reaction reaction were as the object in this experiment. The procedure was divided into two steps are cyclohexanol oxidation reaction and oxidation- reduction of aldehyde by Base Catalyst: Cannizzaro Reaction. The data obtain  are cyclohexanon as the result of cyclohexanol oxidation is 4.80 mL and has boiling point of 153oC with percent yield is 70.86%;  the white crystal of benzoic acid resulted is 3.11 gram with percent yield is 69.84%; and the benzyl alcohol resulted is 2.8 mL and has boiling point of 205oC with percent yield is 73.87%.

Key words: Oxidation reaction, Cyclohexanol, Cannizzaro reaction, Benzaldehyde.

Rabu, 16 Oktober 2013

Analysis of Nucleophilic and Electrophilic Substitution Reaction of Tertiary Butanol and Bromobenzene

ANALYSIS OF NUCLEOPHILIC AND ELECTROPHILIC SUBSTITUTION REACTION OF TERTIARY BUTANOL AND BROMOBENZENE

By
Ni Luh Gede Enik Karnila Yanti
Chemistry Education Department, Faculty of Mathematics and Natural Sciences, Ganesha University of Education
email: enikkarnilayanti@yahoo.co.id

Abstract

The aims of the experiment was to (1) undertand the electrophilic substitution reaction of bromobenzene and nuchleophilic substitution reaction of tert-butyl alcohol (2) identify the products of those reactions. The compound used are tertiary buthanol and bromobenzene were prepared by the laboratory assistant as the subjects of this experiment. The mechanism and the product of the substitution reaction were as the object in this experiment. The procedure was divided into two steps are electrophilic and nuchleophilic substitution reaction. Then, identification of products was done by comparing the physical and chemical properties of the products with theory. Based on comparison, it was known that this experiment produced exactly the same compound as the theory. The electrophilic substitution reaction produced result of 4– bromonitrobenzene while the nucleophilic substitution reaction produced result of tert-butyl chloride.
Key words: Nucleophilic substitution reaction, electrophilic substitution reaction, 4–bromonitrobenzene; tert-butyl chloride.

Rabu, 02 Oktober 2013

Senin, 23 September 2013

Chemistry of Iron Cobalt and Nickel

CHEMISTRY OF IRON, COBALT AND NICKEL

Group VIIIB in the periodic system are divided into 3 sub groups. That vertically called triad transition. In the modern periodic system, this third triad transition was given new classification, namely no. 8, 9, and 10. But the tendency of properties especially their chemical properties horizontally have more similarities than vertically. So it is grouped again into 3 groups of horizontal, each consisting of 3 elements. Iron, cobalt, and nickel are an element contained horizontally in the transition group VIIIB. These elements tends to have similar properties so that they can mix and form an alloy. This essay will briefly discusses about the history, abundance, isolation, properties, uses, iron, cobalt and nickel alloys and its compound namely the oxides; the metallates; the sulfides, selenides and tellurides; the halides and oxohalides; and the complexes.

Endothemic and Exothemic Reaction

ENDOTHERMIC AND EXOTHERMIC REACTIONS

By : Ni Luh Gede Enik Karnila Yanti
Chemistry Education Departement
Faculty of Mathematics and Natural Sciences
Ganesha University of Education

Abstract
Endothermic reaction is the reactions that release heat energy and exothermic reaction is the reactions that absorb heat energy. Heat energy is a form of energy that was received by an object, which causes the temperature of the object, is changed shape. The objective of this experiment was to differentiate endothermic and exothermic reactions. Endothermic reactions are show by decreasing of temperature. Exothermic reactions are show by increasing of temperature.

Key word: endothermic reactions, exothermic reactions